It certainly is nice, best girl among best girls? Yeah, let's not go there... As
@Neil.T mentioned, hopefully we'll come across it during our re-watch but it did invoke The of End of Evangelion for me as well, or one of the latter episodes in the TV series (like 21 maybe?) on the basis of the expression as opposed to outfit heh, so yeah I'd therefore bet on
@Neil.T's more accurate suggestion.
Episode 12 touches on Misato's motivations for her dogged & fierce determination to stick it to the angels. Expands to those of Shinji's and Misato also drops a subtle bomb on why he rubs Asuka up the wrong way. These unpretentious ruminations on the human psyche are what I adore about this show, regardless of the great lore, action, animation etc. with their shortcomings aside, though unsurprisingly they undoubtedly help it along to achieve masterpiece status. On that note:
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Love this scene, with the sound effects of the air as the lift exits an enclosed tunnel, the silhouettes & movement of the elevator relative to the Evas in the distance - fantastic. There was another great scene with some of the lovely soundtrack when Shinji was reminiscing his conversation with Misato overlooking Tokyo-3 at sunset. And the animation of the Evas running and jumping vast distances was also brilliant, great stuff. Lastly, watching on Netflix I've had the alternative music for the closing credits (one of the Rei tracks I believe), which I always thought suited the general feel of the show and the credits scene itself quite well. And though I will always love & prefer the original versions of Fly me to the Moon, and how they often provide a welcome interlude from the melancholia of the heavier episodes, I actually feel objectively the Rei track fits better!