Personal Favourites?
Well I really love Crest of the Stars (13 part series), but it's not available in the UK (there's also 2 more series, Banner of the stars I & II, which follow on from it, but I haven't gotten those. At least, not yet). If you like your in-detph sci-fi / space opera stuff, then this is definitely for you.
RahXephon is really good (26 episode series). Just ignore the people who keep trying to compare it to Evangelion. :mrgreen:
Patlabor 1 & 2. Both very intelligent movies, the 2nd movie particularly, is quite complex and political.
Trigun (another 26 episode series). It's basically a sci-fi space western, set on a desert planet under 2 suns. It's about an incredible gunman with a $$600,000,000,000 bounty on his head. I won't say more than that though at risk of spoiling it. It's funny and cool.
Then there's Cowboy Bebop, which by now is pretty much a legendary series in animé circles. 4 bounty hunters (and a dog) tooling around space, jusr trying to make ends meet. And if that means blowing stuff up, then so be it. :mrgreen:
Actually, there's a lot of stuff I could go on about that I really like. Last Exile, Hellsing, Miyazaki movies (slipped my mind while I was typing), Read or Die... All those animé deserve to have volumes said about them, but you can probably read it elsewhere.